Mark I was wondering what type of Topology you were after
- Coincidence
- Connectivity
- Adjacency
- Containment
Depending on what you are after there are options. If you are just after Coincidence then map topology can be your answer for the editing environment. If you are after some of the others then the OpenSource environment can assist. GRASS is a good option, Oracle have Topological Functions if you use the SDO datatype, as to some of the other Spatial databases. But in my opinion the easiest solution is ArcEditor as you seem to already know the interface. There is also an Extension call GIS Data Reviewer which can be used for Topological verification of features but it is also a paid environment. It is meant to be used for QA/QC in conjunction with core Topology but it does offer some features for things like Checks on Shapefile
--for full disclosure I am an ESRI Distributor Employee but don't let that put you off