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On the assumption that you are using ArcGIS 10.0 SP1 (or later) for Desktop, my quick research turned up an ArcGIS Discussion Forum posting entitled Help - Large file sizes exporting to PDF using ArcPy that looks to be relevant. [At 10.0] SP1, with ExportToPDF and ExportToEPS, we added Adaptive and JPEG compressions. We also added the ...
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