looking at this again, I think you've got it working :-)
some of the long-haul routes are showing up as curved, although it's difficult to see - there are a lot of short-haul routes in there.
Reducing line opacity can sometimes help with this sort of visualisation (or making shorter routes more transparent)
When zoomed far in, great circles tend to look linear - you'll typically only see curvature over hundreds or thousands of Kilometers. If you zoom out, the curves should appear as you expected.
EDIT: I see you want to maximise the curviness of the lines at the scale you're showing.
For this you probablymight need to digitise curves manually. See answers to this question, especially this one
Also, I see PostGIS can convert linestrings to curves e.g. ST_LineToCurve. I haven't tried this but it might be worth looking at.. if you change the control points you might be able to alter the curvature. (Not sure if CARTO supports curves, but you can always change the curves back to linestrings)