QNEAT3 output when selecting fastest path is in seconds, representing the travel time.
Shortest path: the output is in layer units, so it depends on the CRS of your layer. Be sure to have your layer in a CRS where distance measurements makes sense (projected CRS, one that is valid for your region of research). To find a suitable CRS, see here: https://gis.stackexchange.com/a/382608/88814
To find out the CRS of your layer: Right click layer, Properties, Information tab, see screenshot (be aware: EPSG:3857
is not apt to measure distances!):