There are many ways to get thermal data, firstly, you can use a manual radiometer like FLIR which is composed of a thermal camera, you can scan materials with that tool targeting every angle of an object, the main advantage is the low cost and the fact that you can scan materials any time of the day, secondly, using a multispectral camera mounted on an plane or UAV in order to get thermal imagery from above, the main advantage of this method is you can fly any time of the day, you can point your camera in angles, an so you can see oblique images, thirdly, processing Landsat or ASTER satellite imagery, some images are free to download (EarthExplorer), you can get images for a whole city, main disadvantage is the resolution is lower and the time of the day when the satellite collects the data do not correspond to the time when the materials are emitting the higher temperature, also the dates when you can get cloud free imagery is limited.