I'll try to answer even though this was a few years ago.
I suspect that the two rasters are misaligned because the GRASS region was slightly different when you imported the NDVI and LANDSCAPE rasters. I've run into the same issue with many of my rasters, especially when I've imported them during different sessions.
First set and save a permanent region with
g.region -s res=30 raster=yourraster save=file\name. You can set the region however like, whether that is with bounds, vector/raster maps, specifying 2D resolution, etc.
This image shows the landclass raster map to which I set the region and the centroids of the cells:
Here is another landclass raster that was imported while the region was set slightly differently. You can probably see how the cell centroids of the first image don't line up.
Then resample all of your rasters with
r.resample. I believe this uses a nearest neighbor approximation. For my integer rasters, all of the stats and remain the same between the misaligned and aligned raster. It should do the same for floating point rasters. If there is a concern, maybe multiply the floating point to an integer with
r.mapcalc prior to resampling.
Now the resampled landclass raster lines up with the cell centroids from the original raster map.
Just make sure to remember what region setting you are using. If possible, save a default region in PERMANENT or save the region to a file.