The second image represents how I want it to be(Seperated with labels).
How can I add Labels to ArcGIS Online to seperate my fields?
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While I do not believe it is possible to add subsets of fields within the AGOL (ArcGIS Online) environment, a potential workaround is modifying the alias of each field participating in the label, e.g.
Label 1 Governate
Label 1 District
Label 1 Village_Town
Label 2 ID
If I misunderstood your question and you were looking to add additional fields e.g. Label 1, Label 2 in between your fields (in the order you showed in your second image) please respond and I can provide that info for you.