TileStache will definitely do it, specifically the PostGeoJSON provider in the extra providers collection. The main difference between this and what we did for the Polymaps examples is polygon clipping - after seeing how large Alaska can get at higher zoom levels, we clipped all the features in the Polymaps examples to cut down on load times and so on. We also hosted them out of AppSpot to make it possible to add the Access-Control-Allow-Origin header for cross-domain permissions.
PostGeoJSON doesn't clip out of the box, but as it says in the docs I'd be happy to develop the code further if there's interest!
Update: It appears that as of Tilestache 1.9.0 the Vector Provider appears to be favored over the PostGeoJSON Provider.