You could use the Intersect function (Vector > Geoprocessing Tools > Intersect) to provide you with another line layer with duplicates. You can then give your 2 layers different colours (eg. make the original layer to be thicker and darker; the intersect layer to be thinner and lighter).
If you want to see the duplicates in a single line layer then you can use the Merge shapefiles to one function (Vector > Data Management Tools > Merge shapefiles to one). Before you do this, make sure you add an additional attribute to each layer. You can then use the Rule-based style filtering in the merged layer to differentiate between the original layer and the merged layer.
Hope this helps.